Precision spectroscopy of Casimir-Polder molecule-surface interactions

Precision spectroscopy of Casimir-Polder molecule-surface interactions

Keywords:
Casimir-Polder interactions, molecular physics and spectroscopy, sub-wavelength confinement of quantum emitters.

Scientific description:
Interactions between neutral but polarizable objects are essential for the cohesion of matter and play a vital role in our understanding of the electromagnetic properties of matter. One paradigm is the Casimir force between two parallel plates, representing a macroscopic manifestation of quantum fluctuations. Closely related are Casimir-Polder (CP) interactions between a dielectric surface and a quantum object (atom or a molecule) that become important in the nanometric regime.

The SAI group of the LPL has developed selective reflection and nanocell spectroscopy as two major methods for probing Casimir-Polder interactions with excited state atoms. Using these techniques, the group has pioneered atom-surface interaction studies focusing on temperature effects [A. Laliotis et al., Nature Communications, 5, 4364 (2014)] that allow probing surface polaritons with atoms [J. C de Aquino Carvalho et al., Phys. Rev. Lett. 131, 143801, (2023)].

The group has now turned its attention to performing the first precision CP measurements with molecules. Molecule-surface interactions are of fundamental interest allowing us to study the chirality of quantum vacuum and Casimir-Polder anisotropy. The SAI group has probed molecular gases close to dielectric surfaces via selective reflection [J. Lukusa Mudiayi et al. Phys. Rev. Lett. 127, 043201 (2021)] or nanocell spectroscopy [G. Garcia-Arellano et al. Nature Communications, 15, 1862 (2024)]. These results allow the study of sub-wavelength confined molecules but have not yet provided a CP measurement.

We are now offering an internship on a new project that aims at probing an HF gas confined inside a nanocell. Our theoretical calculations have revealed HF to be the ideal molecule for CP measurements due to its linear geometry, simplicity and strong transitions at 2,5μm. We are looking for a motivated student to participate in the building of the experiment, detect the first spectroscopic signals and probe Casimir-Polder interactions of HF molecules confined in the nanometric regime. The student will work with H. Mouhanna (postdoc). The intern could also be involved in theoretical calculations of HF-surface interactions in collaboration with the theory group of Stefan Scheel (Universität Rostock, Germany).

Techniques/methods in use: Quantum electrodynamics, atomic and molecular physics, calculations of atomic and molecular spectra, high-resolution laser spectroscopy.
Applicant skills: Experimental skills, good theoretical background in physics and optics.
Duration: from March 2025 till July 2025 (exact dates flexible).
Internship supervisor(s) Athanasios Laliotis

People involved in project: Isabelle Maurin, Hyppolyte Mouhanna, Paolo Pedri
Internship location: Laboratoire de Physique des Lasers, Université Sorbonne Paris Nord
Possibility for a Doctoral thesis: Yes (Ecole Doctorale Galilée)

You will find the job description here

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